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Meanwhile, her husband looked dapper in a tuxedo and bow tie.
The couple later took to the stage at the awards together to honour the biggest scientific achievements of the year.
PICS: EXCLUSIVE: Mila Kunis Spotted for First Time After Marrying Ashton Kutcher "I think I'll just keep it simple and say break a leg, and I know it's going to be amazing," Ashton said in the video recorded by ET earlier that day.
"You have nothing to be nervous about, and you look stunning."Mila's reaction was priceless.